Synthesis of diethyl trimethylsilyl (trimethylsilylimido) phosphate

MA Pudovik, SA Terent'eva, AN Pudovik

文献索引：Pudovik; Terent'eva Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 993 - 993

全文：HTML全文

被引用次数: 0

摘要

At present two methods of synthesis of dialkyl trimethylsilyl (trimethylsilylimido) phosphates have been described: exhaustive silylation of dialkyl imidophosphate with chlorotrimethylsilane in the presence of bases and the reaction of phosphorus acid chlorides with sodium or lithium bis (trimethylsilyl) amides [1, 2]. According to published data, the reaction of dialkyl (aryl) chlorophosphates with hexamethyldi silazane is accompanied by ...