Inorganic Chemistry

Examination of the reactivity of bis (trifluoromethyl) tellurium: oxidative trifluoromethylations and ligand exchanges with Group 5A and 6A (15 and 16) elements and …

EA Ganja, JA Morrison

文献索引：Ganja, E. A.; Morrison, J. A. Inorganic Chemistry, 1990 , vol. 29, p. 33 - 38

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被引用次数: 11

摘要

Bis (trifluoromethy1) tellurium reacts with 12, Sg, Se, P4, and As at 220 OC to afford CF31,(CF3) 2S,(CFJge,(CF3), P, and (CF,),?, which are separated in 97, 92, 92, 70, and 46% yields, respectively. The interaction of (CFJ2Te with Sb at 170 OC results in very small amounts of (CF3), Sb, ca. 3%, but no (trifluoromethy1) germanes were observed when (CF3) 2Te was exposed to Ge at 170 OC. At 170'C the reactions of (CF,), Te with SeBr,, PI3, and ...