Tetrahedron letters

Heterolytic decarboxylation involving acyltrifluoroacetyl peroxide intermediates

…, IV Kolomitsyn, EM Botov, RM Carlson, IG Semenova…

文献索引：Krasutsky, Pavel A.; Kolomitsyn, Igor V.; Botov, Evgenij M.; Carlson, Robert M.; Semenova, Irina G.; Fokin, Andrey A. Tetrahedron Letters, 2002 , vol. 43, # 48 p. 8687 - 8691

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被引用次数: 7

摘要

Selective carboxylic acid decarboxylation was elaborated. Generation of acyltrifluoroacetyl peroxides from carboxylic peracids and trifluoroacetyl anhydride (Method A), as well as from trifluoroperacetic acid and acyltrifluoroacetyl anhydride (Method B), leads to simultaneous peroxide decomposition into the corresponding alkyltrifluoroacetates. DFT computations, as well as experimental data, support an acid-catalyzed heterolytic mechanism for ...