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Tetrahedron Letters

Sol-gel entrapped chromium (VI): a new selective, efficient and recyclable oxidizing system

M Gruttadauria, LF Liotta, R Noto, G Deganello

文献索引:Gruttadauria, Michelangelo; Liotta, Leonarda F; Noto, Renato; Deganello, Giulio Tetrahedron Letters, 2001 , vol. 42, # 31 p. 5199 - 5201

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被引用次数: 6

摘要

The sol-gel entrapment of chromium (VI) within a silica matrix, obtained by oxidation with ozone of the corresponding entrapped chromium (III), was found to be an efficient and recyclable oxidizing system (at least up to 16 times) for benzylic alcohols. No leaching of chromium in solution was observed, which prevented any environmental pollution.