REACTIONS OF PERFLUOROALKANE-SULFONYL CHLORIDES WITH SILYL ENOL ETHERS CATALYZED BY A RUTHENIUM (II) PHOSPHINE COMPLEX

N Kamigata, K Udodaira, T Shimizu

文献索引：Kamigata, Nobumasa; Udodaira, Kumiko; Shimizu, Toshio Phosphorus, Sulfur and Silicon and Related Elements, 1997 , vol. 129, p. 155 - 168

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被引用次数: 15

摘要

Abstract Reactions of trifluoromethane-and tridecafluorohexanesulfonyl chlorides with silyl enol ethers have been investigated in the presence of a ruthenium (II) phosphine complex. Perfluoroalkylation and chlorination occurred depending on the substituent of silyl enol ether; ie perfluoroalkylated compound was selectively obtained in the reactions with silyl enol ether possessing an electron-withdrawing group, on the other hand, chlorinated ...