Australian Journal of Chemistry

Intramolecular Oxidative Coupling of Aromatic Compounds. VII. A Convenient Synthesis of (±)-Deoxyschizandrin

AR Carroll, RW Read, WC Taylor

文献索引：Carroll, Anthony R.; Read, Roger W.; Taylor, Walter C. Australian Journal of Chemistry, 1994 , vol. 47, # 8 p. 1579 - 1590

全文：HTML全文

被引用次数: 13

摘要

Abstract A convenient synthesis of (±)-deoxyschizandrin was achieved through the key step of reductive coupling of the bisacetonylbiphenyl (3). The latter compound was synthesized by oxidative cleavage of the bis olefin (5) formed by Claisen rearrangement of the bismethallyl ether of 2, 2′, 4, 4′-tetramethoxybiphenyl-3, 3′-diol. The synthesis of 2, 2′, 4, 4′-tetramethoxy-6, 6′-di (prop 1-enyl) biphenyl-3, 3′-diol (2) is also described. The ...