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Tetrahedron

Synthesis of nitrile-terminated potential molecular electronic devices

SM Dirk, JM Tour

文献索引:Dirk, Shawn M.; Tour, James M. Tetrahedron, 2003 , vol. 59, # 3 p. 287 - 293

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被引用次数: 48

摘要

Several potential molecular devices have been synthesized consisting of oligo (phenylene ethynylene)(OPE) backbones containing a terminal nitrile group alligator clip as a means of attachment to a metal surface. The synthesis of four new nitrile-containing OPEs is discussed, including an improved synthesis of an intermediate used in our prior production of OPEs containing acetate-protected thiol alligator clips.