Contributions to the chemistry of silicon-sulphur compounds: XLII. Bis (1-methyldibenzosilole) sulphide: its synthesis, crystal structure, and reaction with chromium …

…, W Wojnowski, K Peters, HG von Schnering

文献索引：Becker, B.; Corriu, R. J. P.; Henner, B. J. L.; Wojnowski, W.; Peters, K.; Schnering, H. G. von Journal of Organometallic Chemistry, 1986 , vol. 312, p. 305 - 312

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被引用次数: 14

摘要

Abstract The reaction of 1-methyldibenzosilole with elemental sulphur gave almost quantitatively bis (1-methyldibenzosilole) sulphide (I), the structure of which was determined by X-ray diffraction. The crystals are monoclinic, space group P2 1/n (No. 14) with a 1772.8 (3), b 921.6 (3), c 1417.5 (2) pm, β 102.09 (1) and Z= 4. The molecule is bent, with an Si S Si bond angle of 108.8 (1).