Iodine/Water??Mediated Oxidation of o??Alkynylaroyl Compounds and Application of the Products of Oxidation in the Synthesis of Nitrogen Heterocycles

K Sakthivel, K Srinivasan

文献索引：Sakthivel, Karuppusamy; Srinivasan, Kannupal European Journal of Organic Chemistry, 2013 , # 16 p. 3386 - 3396

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被引用次数: 5

摘要

Abstract A facile iodine/water-mediated oxidation of the triple bond of o-alkynylaroyl compounds to furnish tricarbonyl compounds is reported. The reaction proceeds through the formation of isochromenol intermediates by the assistance of the neighbouring aroyl group. The product tricarbonyl compounds are versatile synthetic precursors that, upon treatment with mono-and diamines, hydrazines and amino alcohols, afford various heterocyclic ...