New dihydrogen complexes: the synthesis and spectroscopic properties of iron (II), ruthenium (II), and osmium (II) complexes containing the meso-tetraphos-1 ligand

…, PA Maltby, RH Morris, CT Schweitzer

文献索引：Bautista, Maria Teresa; Earl, Kelly Anne; Maltby, Patricia Anne; Morris, Robert Harold; Schweitzer, Caroline Theresia Canadian Journal of Chemistry, 1994 , vol. 72, # 3 p. 547 - 560

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被引用次数: 23

摘要

The synthesis and properties of dihydrogen complexes trans-[MH (H2) L]+, M= Fe, Ru, Os, which contain the ligand meso-tetraphos-1, S, R-Ph2PCH2CH2P (Ph) CH2CH2P (Ph) CH2CH2PPh2 (L) are described. There are interesting possibilities of isomerism in such trans complexes because the axial binding sites at the metal are different, one being surrounded by four phenyl groups and the other by two phenyl groups. The osmium ...