Chemistry Letters

A New one-pot synthesis of thiocarbamates from isocyanates and disulfides in the presence of Zn/AlCl3 System

B Movassagh, Y Zakinezhad

文献索引：Movassagh, Barahman; Zakinezhad, Yousef Chemistry Letters, 2005 , vol. 34, # 10 p. 1330 - 1331

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被引用次数: 23

摘要

A novel method has been developed for the synthesis of S-alkyl (aryl) thiocarbamates. The route involves, first, the formation of zinc thiolates by reductive cleavage of disulfides in the presence of Zn/AlCl 3 system; then subsequent reaction of the thiolate anions with isocyanates gives the desired thiocarbamates in high to excellent yields.