Catalysis letters

Catalytic Asymmetric Transfer Hydrogenation of Ketones Using [Ru (p-cymene) Cl2] 2 with Chiral Amino Alcohol Ligands

SH Deshpande, AA Kelkar, RG Gonnade, SK Shingote…

文献索引：Deshpande, Sudhindra H.; Kelkar, Ashutosh A.; Gonnade, Rajesh G.; Shingote, Savita K.; Chaudhari, Raghunath V. Catalysis Letters, 2010 , vol. 138, # 3-4 p. 231 - 238

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被引用次数: 12

摘要

Abstract Catalytic asymmetric transfer hydrogenation of aromatic alkyl ketones has been investigated using [Ru (p-cymene) Cl 2] 2 and new derivatives of β-amino alcohols synthesized from (S)-(−)-lactic acid and mandelic acid as ligands. Chiral secondary alcohols were obtained with good to excellent conversion (60–90%) and moderate to good enantioselectivities (40–86%). Graphical Abstract Asymmetric transfer hydrogenation of ...