1, 4-Carbosilylation of 1, 3-dienes via palladium catalyzed three-component coupling reaction

Y Obora, Y Tsuji, T Kawamura

文献索引：Obora, Yasushi; Tsuji, Yasushi; Kawamura, Takashi Journal of the American Chemical Society, 1995 , vol. 117, # 39 p. 9814 - 9821

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被引用次数: 70

摘要

Abstract: Three-component coupling reaction of acid chlorides, organodisilanes, and 1, 3- dienes achieves 1, 4-carbosilylation of the 1, 3-dienes to afford allylic silanes as the product. Bis (dibenzylideneacetone) palladium, a naked Pd (0) complex without donating ligand, showed high catalytic activity. A carbon and a silicon substituent are introduced at 1-and 4- positions of the 1, 3-dienes regio-and stereoselectively with concomitant decarbonylation ...