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Concerning the structure of “Acetonepyrrole”

P Rothemund, CL Gage

文献索引:Rothemund; Gage Journal of the American Chemical Society, 1955 , vol. 77, p. 3340

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被引用次数: 112

摘要

The acid-catalyzed reaction of pyrrole and acetone yields “acetonepyrrole,” CSH~~ N~.~ A structure has been proposed by Chelintzev and Tronov (I) 2d and given the name a, P, yJ- octamethylporphinogen by F i~ cher.~ This configuration is based on the isolation of maleimide by oxidation with chromic acid3d and pyrrole and 2-isopropylpyrrole by a pyrolytic reaction. 2b The uncertainty of the linkage of the bridge carbons to the pyrrole ...