Resonance Raman spectra of dioxygen adducts of cobalt porphyrin-imidazole complexes. Remarkable spectroscopic consequences of hydrogen bonding of the …
LM Proniewicz, A Bruha, K Nakamoto…
文献索引:Proniewicz, Leonard M.; Bruha, Alan; Nakamoto, Kazuo; Kyuno, Eishin; Kincaid, James R. Journal of the American Chemical Society, 1989 , vol. 111, # 18 p. 7050 - 7056
Abstract: Resonance Raman (RR) spectroscopic studies of O2 adducts of the imidazole complexes of a highly protected cobalt-porphyrin are reported. Strategic isotopic labeling studies, employing dioxygen isotopomers and selectively deuteriated imidazole analogues, are used to document and interpret the complicated spectral patterns that emerge as a result of complex vibrational coupling of~(0-0) with internal modes of the trans-coordinated ...