Nucleophilic addition and substitution reactions between the cyanide ion and cyclopentadienyliron complexes of chlorobenzenes. Syntheses of benzonitriles and …
RG Sutherland, CH Zhang, A Piórko…
文献索引：Sutherland, Ronald G.; Zhang, Chun-Hao; Piorko, Adam; Lee, Choi Chuck Canadian Journal of Chemistry, 1989 , vol. 67, p. 137 - 142
Reaction of cyclopentadienyliron (CpFe) complexes of chlorobenzenes with NaCN in DMF could give rise to products resulting from the addition of the cyanide ion or from substitution and addition reactions with the cyanide ion. Demetallation-oxidation of such products by treatment with DDQ would lead to the synthesis of benzonitriles and phthalonitriles. With the CpFe complex of chlorobenzene, reaction with NaCN in DMF for 3 min, 30 min, or 3 h ...
