Copper (II)-Mediated Oxidative Coupling of 2-Aminonaphthalene Homologues. Competition between the Straight Dimerization and the Formation of Carbazoles◊

…, V Langer, LJ Farrugia, P Kočovský

文献索引：Vyskocil; Smrcina; Lorenc; Tislerova; Brooks; Kulagowski; Langer; Farrugia; Kocovsky Journal of Organic Chemistry, 2001 , vol. 66, # 4 p. 1359 - 1365

全文：HTML全文

被引用次数: 29

摘要

Whereas the Cu (II)-mediated oxidative coupling of 2-aminonaphthalenes 7a and 7b results in the clean formation of 1, 1'-binaphthyls 13a and 13b, respectively, their higher homologues and congeners 8-12 have been found to exhibit a different reaction pattern. Thus, 2-aminoanthracene (8) gave a~ 1: 1 mixture of the expected bianthryl derivative 15 and the carbazole 16, whereas the 9-aminophenanthrene (10), 3-phenyl-1- ...