The reductive acylation of organic disulfides with aldehydes under photochemical and radical conditions.

M Takagi, S Goto, M Tazaki, T Matsuda

文献索引：Takagi, Makoto; Goto, Setsuo; Tazaki, Masato; Matsuda, Tsutomu Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 7 p. 1982 - 1987

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被引用次数: 18

摘要

The irradiation of organic disulfides in aldehyde solvents resulted in the reductive fission of the S–S linkage, giving an equimolar mixture of the corresponding thiol and the thiol acylate in a good yield. The cyclic disulfides gave mono S-acylated dithiols. The reaction proceeded by means of the photo-initiated radical chain mechanism, and AIBN (azobisisobutyronitrile) effected the same reaction under thermal conditions.