On the mechanism of the thermal Cope rearrangement of allyl-substituted cyclopropenes

A Padwa, TJ Blacklock

文献索引：Padwa,A.; Blacklock,T.J. Journal of the American Chemical Society, 1978 , vol. 100, p. 1321 - 1323

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被引用次数: 14

摘要

925 and YC~ C 1790 cm-'). 2 Further substantiation of the stoichiometry of the reaction between 1 and C2Hz in CH2Cl2 was provided by examining the variation in molar absorptivity at 490 nm that accompanies changing the pressure of C2H2 over the solution at 25 OC. The relationship between the apparent molar absorptivity (eapp), the molar absorptivities of 1 and 2 (e1 and el, respectively), the pressure of C2H2, and the ...