Synthesis and Optical Resolution of the Floral Odorant (±)??2, 3??Dihydro??2, 5??dimethyl??1H??indene??2??methanol, and Preparation of Analogues

…, G Bernardinelli, P Schneider, M Aizenberg…

文献索引：Vial, Christian; Bernardinelli, Gerald; Schneider, Philippe; Aizenberg, Michael; Winter, Beat Helvetica Chimica Acta, 2005 , vol. 88, # 12 p. 3109 - 3117

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被引用次数: 9

摘要

Abstract The title compound (±)-1, a recently discovered, valuable, floral-type odorant, has been synthesized by a straightforward procedure (Scheme 1). To determine the properties of the enantiomers of 1, their separation by preparative HPLC and the determination of their absolute configuration by X-ray crystallography were carried out (Figure). Furthermore, the analogues 2–6 were synthesized, either from differently methylated 2-methylindan-1-ones ...