Propellanes. 16. Bridgehead olefin formation via 11, 11-dihalo [4.4. 1] propellane solvolysis

PM Warner, RF Palmer, SL Lu

文献索引：Warner,P.M. et al. Journal of the American Chemical Society, 1977 , vol. 99, # 11 p. 3773 - 3778

被引用次数: 12

摘要

Abstract: 11, ll-Dibromo-(la), 11, ll-dichloro-(lb), and 11-chloro-1 l-bromo [4.4. 1] propellane (IC) have been hydrolyzed in various aqueous acetone mixtures. The products include the previously reported rearranged bicyclo [5.4. 0] undec-1 (7)-en-2-one (2), 6- halomethylenecyclodecanones (3, 26), 7-hydroxybicyclo [5.4. 0] undecan-2-one (25), 1 l- chlorobicyclo [4.4. llundecane-1, 6-diol (24), and several decalyl carboxylic acids (27, 28, ...