A highly efficient catalytic system for microwave-assisted Suzuki–Miyaura reactions as well as room temperature homocoupling reactions of arylboronic acids in …
A Tairai, C Sarmah, P Das
文献索引：Tairai, Archana; Sarmah, Chandan; Das, Pankaj Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2012 , vol. 51, # 6 p. 843 - 848
Abstract: An in situ generated catalytic system derived from PdCl 2 and (C 6 H 5) 3 CNH 2 shows good-to-excellent activity (upto 92% isolated yield) in the microwave-assisted Suzuki- Miyaura cross-coupling reactions of aryl halides with arylboronic acids in aqueous media. Both electron-donating and electron-withdrawing aryl bromides can be efficiently coupled with arylboronic acids. Chloroarenes can also be coupled, but much lower yields are ...
