Tetrahedron

Medium-sized cyclophanes—XII: Syntheses, variable temperature PMR spectra, and conformational aspects of [mn] metacyclophane sulfur analogs—the effect of ring …

T Sato, M Wakabayashi, K Hata, M Kainosho

文献索引：Sato,T. et al. Tetrahedron, 1971 , vol. 27, p. 2737 - 2755

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被引用次数: 47

摘要

The preparation of [mn] metacyclophane sulfur analogs with ring size up to 14 are described. They include 11-and 12-membered sulfides, sulfoxides, and sulfones as well as 12-and 14-membered rings having disulfide linkages. Through PMR spectral studies, including variable temperature spectroscopy, their conformation and conformational mobility are examined in relation to structural variation. While the parent compound of this series,[2 ...