Two-step synthesis of triarylmetals (As, Sb, Bi) starting from the metal oxides and 2, 6-dimethoxybenzenethiol

…, S Natsume, S Suzuki, U Akira, M Nakamura…

文献索引：Wada, Masanori; Natsume, Satoko; Suzuki, Shinobu; Uo, Akira; Nakamura, Michiaki; Hayase, Shuichi; Erabi, Tatsuo Journal of Organometallic Chemistry, 1997 , vol. 548, # 2 p. 223 - 227

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被引用次数: 14

摘要

Reported here is a new synthetic method of triarylmetals MAr3 (M= As, Sb, Bi). It is composed of two-step reactions starting from the metal oxides:(1) A reaction of the metal oxide with 2, 6-dimethoxybenzenethiol ΦSH [Φ= 2, 6-(MeO) 2C6H3] in the presence of acid to give the thiolatometals M (SΦ) 3, and (2) A reaction of M (SΦ) 3 with organolithium reagent LiAr to give MAr3 (Ar= Ph, 4-MeC6H4, 4-Me2NC6H4, Φ). Since ΦSH is odorless ...