Journal of organometallic chemistry

Silacyclopropenes: I. Synthesis and properties of some silacyclopropenes

D Seyferth, DC Annarelli, SC Vick

文献索引：Seyferth, Dietmar; Annarelli, Dennis C.; Vick, Steven C. Journal of Organometallic Chemistry, 1984 , vol. 272, # 2 p. 123 - 140

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被引用次数: 44

摘要

Abstract The thermal decomposition of hexamethylsilirane in the presence of selected disubstituted acetylenes (Me 3 SiC CSiMe 3), Me 2 HSiC CSiMe 2 H, Me 3 SiC CCH 3, Me 3 SiC CCMe 3, Me 3 CC CCH 3) resulted in Me 2 Si addition to the C C bonds to give the respective silacyclopropenes. These are thermally stable but are extremely reactive toward atmospheric oxygen and moisture and react readily with methanol and ethanol at ...