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The use of bunte salts in synthesis. II. The preparation of derivatives of mercapto aliphatic acids

GG Stoner, G Dougherty

文献索引:Stoner; Dougherty Journal of the American Chemical Society, 1941 , vol. 63, p. 988

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被引用次数: 14

摘要

Sodium thiosulfate reacts with alkyl halides to form esters of the type RSSOsNa, called Bunte salts. These S-alkyl thiosulfates have been used for preparing neutral mercaptans, 2 dis~ lfides,~ mercaptals4 and mercaptols. 6 This paper describes the use of Bunte salts for directly preparing dicarboxylic acids which are disulfides, mercaptals and mercaptols. Sodium thiosulfate and sodium chloroacetate formed disodium S-carboxymethyl ...