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Synthetic uses of thio-and selenoesters of trifluoromethylated acids. 1. Preparation of trifluoromethyl sulfides and selenides

T Billard, N Roques, BR Langlois

文献索引:Langlois, Bernard; Montegre, Denis; Roidot, Nathalie Journal of Fluorine Chemistry, 1994 , vol. 68, # 1 p. 63 - 66

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被引用次数: 82

摘要

Trifluorothioacetates (CF3CO-SR, from (CF3CO) 2O and thiols) as well as trifluoromethanethio-or trifluoromethaneselenosulfonates (CF3SO2-YR; Y= S, Se; from CF3SO2Na, RYYR, and Br2) can be formally decarbonylated or desulfonylated,