The Journal of chemical physics

T1 barrier height, S1–T1 intersystem crossing rate, and S0 radical dissociation threshold for H2CO, D2CO, and HDCO

MC Chuang, MF Foltz, CB Moore

文献索引：Chuang, Mei-Chen; Foltz, Mary F.; Moore, C. Bradley Journal of Chemical Physics, 1987 , vol. 87, # 7 p. 3855 - 3864

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被引用次数: 128

摘要

Vacuum UV laser??induced fluorescence has been used to detect the atomic products in the photofragmentation of H2CO, D2CO, and HDCO. The dissociation is shown to occur on both the ground (S 0) and the first triplet (T 1) potential surfaces. The T 1 exit barrier height (2.9 ...