Tetrahedron

The hydrocyanation of free and polymer-bound benzoquinone

GJ Perry, MD Sutherland

文献索引：Perry, Gregory J.; Sutherland, Maurice D. Tetrahedron, 1982 , vol. 38, # 10 p. 1471 - 1476

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被引用次数: 8

摘要

The polymer-bound quinone2 has been prepared and used in column form with organic solvents for the convenient preparation of other quinones. In contrast to the solution reaction hydrocyanation of this quinone by the Thiele-Meisenheimer reaction did not yield a useful proportion of polymer-bound dicyanohydroquinone but instead gave a mixture of products including much monocyanohydroquinone. Helferich and Bodenbender's 2, 3- ...