Methacryladehyde Dimer. Derivatives Obtained through the Cannizzaro Reaction1

GG Stoner, JS McNulty

文献索引：Stoner; McNulty Journal of the American Chemical Society, 1950 , vol. 72, p. 1531

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被引用次数: 14

摘要

In common with other a, p-unsaturated alde- Methacrylaldehyde dimer is an aldehyde which hyde~ 3~ 8 bvc and ketones, 3b9d, e methacrylaldehyde has no a-hydrogen. Accordingly, the Cannizzaro (methylpropenal, methacrolein) undergoes a reaction was clean-cut. 6b The expected unsatu-Diels-Alder type4 of reaction with itself to pro-rated acid6b and alc~ hol~~,~(111) isomerized readily duce a dimer5 (I), 3, 4-dihydr0-2, 5-dimethyl-l, 2H-into a ...