Free radical addition of 2-bromoalkanoic acids to alkenes

T Nakano, M Kayama, Y Nagai

文献索引：Nakano, Taichi; Kayama, Mikio; Nagai, Yoichiro Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 3 p. 1049 - 1052

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被引用次数: 9

摘要

The benzoyl peroxide-catalyzed reaction of 2-bromoalkanoic acids such as bromoacetic, 2- bromopropionic, and 2-bromobutyric acid with 1-alkenes was found to proceed through the addition of the C–Br bond across the double bond followed by cyclization affording 4- alkanolides in good yields.