Fe??Catalyzed One??Pot Oxidative Cleavage of Unsaturated Fatty Acids into Aldehydes with Hydrogen Peroxide and Sodium Periodate
P Spannring, V Yazerski, PCA Bruijnincx…
文献索引：Spannring, Peter; Yazerski, Vital; Bruijnincx, Pieter C. A.; Weckhuysen, Bert M.; Klein Gebbink, Robertus J. M. Chemistry - A European Journal, 2013 , vol. 19, # 44 p. 15012 - 15018
Abstract A one-pot method has been developed for the oxidative cleavage of internal alkenes into aldehydes by using 0.5 mol% of the nonheme iron complex [Fe (OTf) 2 (mix- bpbp)](bpbp= N, N′-bis (2-picolyl)-2, 2′-bipyrrolidine) as catalyst and 1.5 equivalents of hydrogen peroxide and 1 equivalent of sodium periodate as oxidants. A mixture of diastereomers of the chiral bpbp ligand can be used, thereby omitting the need for ...
