Transmetallations between aryltrialkyltins and borane: synthesis of arylboronic acids and organotin hydrides

MB Faraoni, LC Koll, SD Mandolesi, AE Zuniga…

文献索引：Faraoni; Koll; Mandolesi; Zuniga; Podesta Journal of Organometallic Chemistry, 2000 , vol. 613, # 2 p. 236 - 238

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被引用次数: 20

摘要

Arylboronic acids are valuable reagents for organic synthesis. Thus, they have lately been employed in the synthesis of achiral and chiral alcohols [1], of diaryl ethers [2], and are also currently used for palladium-catalyzed cross-coupling reactions with organic halides or triflates leading to the formation of carbon-carbon bonds (Suzuki reaction) [3]. The boronic acids are generally prepared via the reaction of boron halides (or esters of boric acid) with organometallic compounds ...