Selective reduction of saturated perfluorocarbons

JA Marsella, AG Gilicinski, AM Coughlin…

文献索引：Marsella,John A.; Gilicinski, Andrew G.; Coughlin, Anne M.; Pez, Guido P. Journal of Organic Chemistry, 1992 , vol. 57, # 10 p. 2856 - 2860

全文：HTML全文

被引用次数: 61

摘要

Perfluorocycloaliphatic compounds are reduced by solutions of the sodium benzophenone radical anion to give perfluorinated and highly fluorinated aromatic compounds. Perfluorocycloalkanes containing tertiary carbon centers are much more reactive than perfluorocyclohexane. Reduction of perfluoroalkanea and perfluorocycloalkanea that contain perfluoroalkyl substituents proceeds easily; however, it appears that overreduction ...