Fluorocarbon halosulfates and a new route to fluorocarbon acids and derivatives. II. Polyfluoroalkyl fluorosulfates

M Hauptschein, M Braid

文献索引：Hauptschein,M.; Braid,M. Journal of the American Chemical Society, 1961 , vol. 83, p. 2505 - 2507

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被引用次数: 21

摘要

I\'ovel reactions of fluorosulfonic acid with fluorocarbon iodides have been discovered by which fluorocarbon fluorosulfates are prepared. The syntheses of CF~ CFZCF~ OSO~ F, CF2ClCFClOS02F and CF~ CFZCF (CF?)(CKZCF&OSOZF and their one-step conversions to CF3CF2CONH2, CF2ClCONHZ and CF3CF2CF (CF3) CH? CF2CH2COKH2 by ammonolysis of the respective fluorosulfates are described.