Studies related to anthracyclines. Part 1. Some Diels–Alder reactions of 4a, 9a-epoxy-4a, 9a-dihydroanthracene-1, 4, 9, 10-tetrone

M Chandler, RJ Stoodley

文献索引：Chandler; Stoodley Journal of the Chemical Society. Perkin transactions 1, 1980 , vol. 4, p. 1007 - 1012

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摘要

The title compound (5b), prepared by the oxidation of anthracene-1, 4, 9, 10-tetrone (4) with m-chloroperbenzoic acid, undergoes Dieels–Aldr reactions with cyclohexa-1, 3-diene, cyclopentadiene, and 2-methylbuta-1, 3-diene to give 5a, 11a-epoxy-1, 4-ethano-1, 4, 4a, 5a, 11a, 12a-hexahydronaphthacene-5, 6, 11, 12-tetrone (7a), 5a, 11 a epoxy-1, 4, 4a, 5a, 11 a, 12a-hexahydro-1, 4-methanonaphthacene-5, 6, 11, 12-tetrone (7b), and 5a, 11a- ...