Catalytic Aerobic Oxidative Cleavage of Oximes, Tosylhydrazones and N, N-Dimethylhydrazones to Carbonyl Compounds

…, E Benach, I Fernandez, S Galletero, JR Pedro…

文献索引：Blay, Gonzalo; Benach, Elisabeth; Fernandez, Isabel; Galletero, Sales; Pedro, Jose R.; Ruiz, Rafael Synthesis, 2000 , # 3 p. 403 - 406

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被引用次数: 7

摘要

Abstract: A new method for the aerobic oxidative cleavage of the C= N double bond of oximes and, tosyl-and N, N-dimethylhydrazones of ketones to yield their corresponding carbonyl compounds, with a Ni (II) complex catalyst, oxygen and pivalaldehyde has been developed. Key words: protective groups, ketoxime, hydrazone, metal catalyst, Ni (II) complex