Autoxidation of biological molecules. 4. Maximizing the antioxidant activity of phenols
GW Burton, T Doba, E Gabe, L Hughes…
文献索引：Burton, G. W.; Doba, T.; Gabe, E. J.; Hughes, L.; Lee, F. L.; et al. Journal of the American Chemical Society, 1985 , vol. 107, # 24 p. 7053 - 7065
Abstract: Rate constants, kl, for H-atom abstraction by peroxyl radicals from a-tocopherol and 35 structurally related phenols have been measured at 30 OC by the inhibited autoxidation of styrene (IAS) method. An independent laser-flash kinetic EPR method was used with ten of these phenols which gave k, values at 24 OC that were in satisfactory agreement with the values found by the IAS method. The structures of several phenols were determined by X- ...
