Stereoselectivity of the generation of 3-mercaptohexanal and 3-mercaptohexanol by lipase-catalyzed hydrolysis of 3-acetylthioesters

…, M Wakabayashi, W Eisenreich, KH Engel

文献索引：Wakabayashi, Hidehiko; Wakabayashi, Motoko; Eisenreich, Wolfgang; Engel, Karl-Heinz Journal of Agricultural and Food Chemistry, 2003 , vol. 51, # 15 p. 4349 - 4355

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被引用次数: 23

摘要

The enantioselectivity of the generation of 3-mercaptohexanal and 3-mercaptohexanol, two potent sulfur-containing aroma compounds, by lipase-catalyzed hydrolysis of the corresponding 3-acetylthioesters was investigated. The stereochemical course of the kinetic resolutions was followed by capillary gas chromatography using modified cyclodextrins as chiral stationary phases. The enzyme preparations tested varied significantly in terms of ...