Reactions of group IV organometallic compounds: XXVII. The insertion reactions of benzoyl-tert-butylcarbodiimide with group IV trimethylmetallylamines and teh …
I Matsuda, K Itoh, Y Ishii
文献索引:Matsuda,I. et al. Journal of Organometallic Chemistry, 1974 , vol. 69, p. 353 - 359
Abstract The insertion of benzoyl-tert-butylcarbodiimide with Me 3 M NMe 2 (M= Si, Ge and Sn) or (Me 3 M) 2 NMe (M= Si and Sn) is described. The pyrolyses of 11 adducts by organosilyl-and organogermyl-amines gave the corresponding Me 3 M N C N CMe 3 (M= Si and Ge) by elimination of N, N-disubstituted benzarnides.