Direct epoxidation of fluorinated olefins using the fluorine-water-acetonitrile system

…, BE Smart, AE Feiring, S Rozen

文献索引：Hung, Ming H.; Smart, Bruce E.; Feiring, Andrew E.; Rozen, Shlomo Journal of Organic Chemistry, 1991 , vol. 56, # 9 p. 3187 - 3189

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被引用次数: 42

摘要

Fluorine-containing epoxides are important intermediates in the synthesis of surfactants, oligomers, and polymers with special properties.'Since most polyfluorinated olefins are too deactivated for direct electrophilic epoxidation, their epoxides are usually made by either using special catalysts or employing indirect methods. For example, our attempts to epoxidize the electron deficient double bond of 3, 3, 4, 4, 5, 5, 6, 6, 6-nonafluorohexene (1 ...