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Canadian Journal of Chemistry

13C nuclear magnetic resonance studies. 58. 13C spectra of a variety of bicyclo [2.2. 2] octane derivatives. Further definition of the deshielding δ effect

JB Stothers, CT Tan

文献索引:Stothers,J.B.; Tan,C.T. Canadian Journal of Chemistry, 1976 , vol. 54, p. 917 - 925

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被引用次数: 33

摘要

The 13C nmr spectra of 35 bicyclo [2.2. 2] octane and-octene derivatives have been determined to extend our examinations of the effects of stereochemistry on the shieldings of closely neighboring carbons. This series includes a variety of methyl substituted bicyclooctanols and-octenols as well as the corresponding hydrocarbons and some bicyclooctanones. With the bicyclo [2.2. 2] octane skeleton it is possible to examine an ...