Onium ions. 26. Aminodiazonium ions: preparation, proton, carbon-13, and nitrogen-15 NMR structural studies, and electrophilic amination of aromatics
GA Olah
文献索引：Mertens, Alfred; Lammerstma, Koop; Arvanaghi, Massoud; Olah, George A. Journal of the American Chemical Society, 1983 , vol. 105, # 17 p. 5657 - 5660
Abstract: Protonation of hydrazoic acid and alkyl azides with FS03H/SbFj, HF/SbF5, or HF/BF3 results in the formation of stable aminodiazonium ions as shown by'H," C, and I5N NMR spectroscopic studies. Molecular orbital calculations of the thermodynamics of the protonation of hydrazoic acid also support preferential formation of the aminodiazonium ion. The aminodiazonium ion was also prepared in situ from NaN3/A1C13/HC1 or (CH3) ...
