Tetrahedron

Structure and conformational processes of bis (o-cumyl) sulfide, sulfoxide and sulfone

L Lunazzi, A Mazzanti, M Minzoni

文献索引：Lunazzi, Lodovico; Mazzanti, Andrea; Minzoni, Mirko Journal of Organic Chemistry, 2005 , vol. 70, # 2 p. 456 - 462

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被引用次数: 7

摘要

The NMR solution spectra of the title sulfide and sulfone show decoalescence of the geminal methyl signals of the isopropyl groups at low temperature (− 178° C for the 13C signal of sulfide at 150.8 MHz and− 147° C for the 1H signal of sulfone at 600MHz). The barriers for