2, 3', 5', 6-Tetra-t-butylindophenoxyl, Competitive Scavenging, and Isotope Effects1

PD Bartlett, ST Purrington

文献索引：Bartlett; Purrington Journal of the American Chemical Society, 1966 ,  vol. 88,  # 14  p. 3303 - 3309

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被引用次数: 16

摘要

Abstract: The stable free radical I1 (BIP), mp 155-156", scavenges short-lived free radicals by direct addition, as does galvinoxyl; the products from t-butoxy and cyanoisopropyl radicals have been characterized. BIP agrees with other good scavengers in indicating cage effects of 38-44% for the decomposition of azobisisobutyronitrile (AIBN) in benzene at 34- 62", and of less than 3% for di-t-butyl diperoxyoxalate (DBPO) at 25". ...