Synthetic Routes to, Transformations of, and Rather Surprising Stabilities of (N-Methyl-N-phenylcarbamoyl) sulfenyl Chloride,((N-Methyl-N-phenylcarbamoyl) dithio) …
AM Schrader, AL Schroll, G Barany
文献索引：Schrader, Alex M.; Schroll, Alayne L.; Barany, George Journal of Organic Chemistry, 2011 , vol. 76, # 19 p. 7882 - 7892
The title compound classes,(carbamoyl) sulfenyl chlorides and ((carbamoyl) dithio) carbonyl chlorides, have been implicated previously as unstable, albeit trappable, intermediates in organosulfur chemistry. The present work reports for each of these functional groups:(i) several routes to prepare it in the N-methylaniline family;(ii) its direct structural characterization by several spectroscopic techniques;(iii) its rather unexpected stability ...
