A study on applications of N-substituted main-chain NHC-palladium polymers as recyclable self-supported catalysts for the Suzuki–Miyaura coupling of Aryl chlorides …
B Karimi, P Fadavi Akhavan
文献索引：Karimi, Babak; Fadavi Akhavan, Pari Inorganic Chemistry, 2011 , vol. 50, # 13 p. 6063 - 6072
The preparation and characterization of main-chain organometallic polymers (NHC-Pd MCOP) with different N-alkyl groups and their application in the Suzuki reaction of aryl chlorides is described. Using compelling evidence, such as kinetic monitoring, poisoning experiments, and average molecular weight determinations before and after catalysis, it has been rationalized that these organometallic polymers might indeed be the source of ...
