143. The constituents of high-boiling petroleum distillates. Part VIII. Identification of 1, 2, 3, 4-tetrahydro-2, 2, 9-trimethylpicene in an American crude oil

W Carruthers, DAM Watkins

文献索引：Carruthers,W.; Watkins,D.A.M. Journal of the Chemical Society, 1964 , p. 724 - 729            

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被引用次数: 16

摘要

Ahydrocarbon isolated by Carruthers and Cook from a fraction of an American crude oil, and shown from its ultraviolet spectrum to be a derivative of chrysene, has been identified as the tetrahydropicene derivative (11). The molecular weight, determined by mass spectroscopy, was 324, in agreement with the formula C, H,,. It was resistant to dehydrogenation with palladium, 2 but with selenium at 350" 2, 9-dimethylpicene (I) was obtained, accounting ...