Organometallics

Deoxygenative coupling of ketones and alkenes by tungsten (II) compounds

JC Bryan, JB Arterburn, GK Cook, JM Mayer

文献索引：Bryan, Jeffrey C.; Arterburn, Jeffrey B.; Cook, Gerald K.; Mayer, James M. Organometallics, 1992 , vol. 11, p. 3965 - 3970

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被引用次数: 12

摘要

Tungsten (I1) compounds such as WC12 (PMePh2) 4 (1) react with acetone and ethylene to give a good yield of the tungsten (1V)-oxo complexes W (0)(CH2= CH2) C12 (PMePh2) z (4) and a moderate amount of 3-methyl-1-butene. Cyclopentanone and ethylene plus 1 yield 4 and vinylcyclopentane; methyl vinyl ketone and ethylene give 4 and 3-methyl-l, 4- pentadiene. The reaction of cyclopentanone and propylene with 1 yields a small amount ...

~30%

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