Synlett

Unexpected chemoselective debromination and reduction of 1, 1-dibromo-1-alkenes mediated by samarium metal in methanol

L Wang, P Li, Y Xie, Y Ding

文献索引：Wang, Lei; Li, Pinhua; Xie, Yuanyuan; Ding, Yanbin Synlett, 2003 , # 8 p. 1137 - 1140

被引用次数: 6

摘要

Abstract An unexpected samarium metal mediated chemoselective debromination and reduction of 1, 1-dibromo-1-alkenes in methanol has been developed, which generates vinyl monobromides, alkenes, and alkanes respectively with appropriate molar ratio of samarium to 1, 1-dibromo-1-alkene.

7436-90-0

(2,2-二溴乙烯基)苯

~97%

~10%

~96%

~98%

~98%

~96%

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